I am not sure about that.
The first thing to say is that we have never tested

We have stopped adding new features to SmartFoxServer 1.x in 2011, when we launched SFS2X. The product (1.x) is still supported, i.e. we fix bugs and potential vulnerabilities, if they are found but we are not adding new features.
Back in 2011 the switch to IPv6 networks was not a worry for developers.
In any case, I think there is nothing in SmartFoxServer PRO that should stop it from running on an IPv6 only network, so the server is hardly the problem.
From a client side perspective (Objective-C API) my first concern is that the last release of Objective-C API is dated June 2010, so I am not sure if they would compile correctly under the latest XCode and iOS targets. You can try and see if they do:
http://smartfoxserver.com/download/sfsPro#p=updates
If they do compile and there's no major show stopper (e.g. deprecated classes etc...) then I think they might work with IPv6, for the simple reason that the low-level networking is handled by Apple's own framework (CFNetwork etc...) which in turn does support IPv6.
The moral of the story is: we don't "support it" because we have never tested it thoroughly.
As I said, the litmus test is trying to compile the old 1.x Objective-C under a modern XCode and see if they work.
Hope it helps